The Removal of Chromium(VI) from Aqueous Solution by Amine-Functionalized Zeolite: Kinetics, Thermodynamics, and Equilibrium Study

Shirendev Nasanjargal, Bat-Amgalan Munkhpurev, N. Kano, Hee-Joon Kim, Yu Ganchimeg
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引用次数: 7

Abstract

In this study, the removal of Cr(VI) from aqueous solution by modified zeolite with 3-aminopropyltriethoxysilane was investigated. The effect of various parameters such as pH, contact time, temperature, initial concentration of Cr(VI) ion, common cations, and anions on the adsorption of Cr(VI) was studied. The modified zeolite was characterized by following instrumental analysis of XRD, SEM/EDS, BET, and FT-IR. Based on calculated thermodynamic parameters values (ΔG0 H0 > 0, and ΔS0 > 0) and kinetic properties of the adsorption of Cr(VI) by modified zeolite, it was concluded that the rate-limiting step of the process is a second-order chemical reaction. The results of the adsorption isotherm study confirmed that the adsorption follows the Langmuir isotherm model. The maximum adsorption capacity was 13.5 mg/g.
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胺官能化沸石从水溶液中去除铬(VI)的动力学、热力学和平衡研究
在本研究中,研究了3-氨基丙基三乙氧基硅烷改性沸石对水溶液中Cr(VI)的去除。研究了pH、接触时间、温度、Cr(VI)离子的初始浓度、常见阳离子和阴离子等参数对Cr(Ⅵ)吸附的影响。通过XRD、SEM/EDS、BET和FT-IR等仪器分析对改性沸石进行了表征。根据计算的热力学参数值(ΔG0 H0>0和ΔS0>0)和改性沸石吸附Cr(VI)的动力学性质,得出该过程的限速步骤是一个二阶化学反应。吸附等温线研究结果证实,吸附遵循Langmuir等温线模型。最大吸附量为13.5mg/g。
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