Performance evaluation of a water erosion tracer using plot-scale experiments and process-based modeling

Abstract

Socioeconomic and environmental losses caused by water erosion have highlighted the importance of quantifying and understanding the dynamics of soil redistribution in the landscape to develop effective soil management practices. Several methods are applied to estimate erosion/deposition rates and identify sources of sediments, among them, the one that uses rare earth elements (REE) as a tracer stands out. However, an alternative not yet explored that can benefit the accuracy of the estimates provided by the method is using a tracer containing a chemical signature composed of more than one REE. The present study aimed to evaluate the performance of a new water erosion tracer based on montmorillonite labeled with rare earth elements (La40-MMT). The innovative aspects of this La40-MMT tracer include its highly stable multi-chemical signature (Nd³⁺, La³⁺, and Pr³⁺), which enhances tracer detection in the environment, and its low production cost due to the use of an industrial residue in the synthesis process. The tracer was evaluated for a typical soil of the Cerrado biome, using a natural rainfall field-scale plot - NRFP (5 m × 20 m) and a physical predictive erosion model (WEPP). The results showed that the La40-MMT tracer could be used to estimate erosion/deposition rates, with agreement between the values observed with the tracer and the WEPP model. Thus, this study confirmed the great potential of La40-MMT as a tool to identify patterns of soil redistribution at the field scale and aid in the validation of erosion models.