Sourcing of chalkstone used in medieval buildings in the Eastern Duchy of Normandy (10th−14th centuries) through geological and geochemistry analyses

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2022-03-20 DOI:10.1002/gea.21907
Daniel Ballesteros, Aude Painchault, Beatriz Puente-Berdasco, Carol Nehme, Dominique Todisco, José Ignacio García-Alonso, M. Varano, D. Mouralis
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引用次数: 2

Abstract

The provenance of medieval building stones links historic constructions with their quarrying areas, thereby revealing medieval trade routes and the spatial organization of past societies. In northern France, the Duchy of Normandy played a significant role in the medieval history of Europe, situated at the centre of the disputes between the English and French kingdoms. However, the historical documentation from this period is scarce, particularly in terms of the quarrying industry. Our study aims to define the quarrying areas and their diffusion zones and map the territorial organization of Eastern Normandy during the 10th–14th centuries. A multidisciplinary procedure using archaeological, geological and geochemical techniques was designed to establish the provenance of Normandy Chalkstone. First, we obtained a representative assembly of building stones by the selection and strategic sampling of 22 buildings. Second, we determined areas of chalk bedrock from a geological map rendered through GIS and sampled chalkstones from natural outcrops and quarries. In total, 118 samples from buildings, quarries and natural outcrops were characterized via optical microscopy and geochemical analyses for major, minor and trace elements (XRF, ICP-MS and ICP-OES), as well as for 87Sr/86Sr isotope ratios (MC-ICP-MS). The application in situ of pXRF analysis allows for the identification of Normandy Chalkstone sources preserved in archaeological sites. The results indicate that all chalkstones came from five local varieties of Normandy Chalkstone and one of Shelly Limestone imported from nearby regions. The suitability of chalkstone as construction material was evaluated in situ using a sclerometer, which revealed that the singular and local geological features of the chalkstone make it suitable for walling. Our study demonstrates the development of a prominent and relatively continued quarrying industry over the 10th to 14th centuries in Eastern Normandy. The main quarrying areas were constituted of three chalkstone diffusion zones that run coevally with smaller and apparently sporadic quarries. The chalkstone diffusion was strongly related to the occurrence of singular and local geological resources and the stone transport system, which favoured the use of effective fluvial and maritime navigation for transport over 50 km from the quarrying areas.

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通过地质和地球化学分析,找到了诺曼底东公国(10 - 14世纪)中世纪建筑中使用的石灰石
中世纪建筑石材的来源将历史建筑与其采石场联系起来,从而揭示了中世纪的贸易路线和过去社会的空间组织。在法国北部,诺曼底公国在欧洲中世纪历史上扮演着重要的角色,位于英法王国争端的中心。然而,这一时期的历史文献很少,特别是关于采石业的文献。我们的研究旨在界定采石场及其扩散区,并绘制10 - 14世纪东诺曼底的领土组织图。利用考古学、地质学和地球化学技术设计了一个多学科程序,以确定诺曼底白垩石的来源。首先,我们通过对22座建筑的选择和策略抽样,获得了具有代表性的建筑石材集合。其次,我们从地理信息系统绘制的地质图中确定了白垩基岩的区域,并从自然露头和采石场取样了白垩岩。通过光学显微镜和地球化学分析(XRF、ICP-MS和ICP-OES),以及87Sr/86Sr同位素比(MC-ICP-MS)对118个建筑物、采石场和自然露头样品进行了特征分析。在现场应用pXRF分析可以识别保存在考古遗址中的诺曼底白垩石来源。结果表明,所有的白垩石均来自5个诺曼底白垩石本地品种和1个从附近地区进口的雪莉白垩石品种。利用硬度计对白垩石作为建筑材料的适用性进行了原位评估,结果表明,白垩石的独特和局部地质特征使其适合于墙体。我们的研究表明,在10至14世纪,东诺曼底有一个突出的、相对持续的采石业的发展。主要采石场由三个白垩石扩散带组成,这些扩散带与较小的、明显零散的采石场共同运行。白垩石的扩散与单一和局部地质资源的出现以及石头运输系统密切相关,这有利于利用有效的河流和海上航运从采石场运输50公里。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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