Directed synthesis and study of their spectroscopic behavior in solution of rare-earth phthalocyaninates substituted by benzyloxy- and methylphenylethylphenoxy-groups
A. A. Botnar, A. N. Bychkova, N. P. Domareva, T. V. Tikhomirova, A. S. Vashurin
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引用次数: 6
Abstract
Novel neodymium phthalocyaninates based on template condensation of 4-[(4-benzyloxy)phenoxy]- or 4-(1-methyl-1-phenylethyl)phenoxyphthalonitriles with neodymium salts were obtained. The most selective preparation of neodymium sandwich complexes was found to occur with neodymium acetate as a template. The spectroscopic properties of neodymium metal complexes synthesized in organic solvents were studied. It was determined sandwich complexes of neodymium forms a mixture of in "blue" and "green" forms in the solution.
期刊介绍：
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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