Half-Sandwich d 6 -Metal (Co III , Rh III , Ir III , Ru II )-Catalyzed Enantioselective C–H Activation

IF 2 Q2 CHEMISTRY, ORGANIC SynOpen Pub Date : 2023-07-25 DOI:10.1055/a-2167-8298
Pu-Fan Qian, Jun-Yi Li, Yi-Bo Zhou, Tao Zhou, Bing‐Feng Shi
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Abstract

Transition metal-catalyzed enantioselective C–H activation has provided a straightforward strategy to synthesize chiral molecules from readily available sources. In this graphic review, we summarized the progress of half-sandwich d6 metal (CoIII, RhIII, IrIII, RuII) catalyzed enantioselective C–H functionalization reactions. The review was categorized according to the types of metal catalysts and chiral ligands. Representative enantio-determining models and catalytic cycles were presented. We hope this graphic review would stimulate further efforts on the development of novel chiral ligands and strategies in this emerging research topic.

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半三明治d 6-金属(Co III,Rh III,Ir III,Ru II)催化的对映体选择性C–H活化
过渡金属催化的对映选择性C-H活化提供了一种直接的策略,从现成的来源合成手性分子。本文综述了半夹层d6金属(CoIII, RhIII, IrIII, RuII)催化对映选择性C-H功能化反应的研究进展。本文根据金属催化剂和手性配体的类型进行了综述。介绍了具有代表性的对映体测定模型和催化循环。我们希望这一图形综述将刺激进一步努力开发新的手性配体和策略在这个新兴的研究课题。
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来源期刊
SynOpen
SynOpen CHEMISTRY, ORGANIC-
CiteScore
2.30
自引率
4.00%
发文量
35
审稿时长
6 weeks
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