Forced heat exchange and cooling rate of drops at producing metal powders by melt water atomizatio

Yu. F. Ternovyi, A. Prigunova, V. Panova
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Abstract

of the technological process for the production of metal products using the powder metallurgy method. Among the wide variety of methods for making powders, in terms of efficiency and productivity, the spraying of melts with high-pressure water is favorably distinguished, in which the geometric shape and microstructure of particles significantly depend on the cooling rate, which is associated with the peculiarities of heat transfer in the melt drop – water – gas phase system. However, experimental confirmation of one or another mode of heat transfer is not possible, which is associated with the small size of particles, the number of which in 1 cm 3 of the spray zone is about 10 7 . The influence of the thermal physics of the sputtering process on the solidification rate of metal droplets is analyzed. Based on the analysis of the known regularities and phenomena of heat and mass transfer, the heat transfer coef-ficients, the heat flux density for various heat transfer modes, as well as the contribution of the conductive, convective and radiation components of heat transfer are estimated. It is shown that the fraction of heat transfer by radiation is no more than 0.1 %. It has been theoretically proven that droplets are cooled in the bubble mode of water boiling. For tool steel, the particle cooling rate calculated on the basis of the heat transfer coefficient in the developed bubble mode is about 10 6 K/s. Such a cooling rate during bubble or pseudobubble boiling is provided when the resulting vapor film is "torn off" by the water flow, simulating "pseudobubble" cooling. The formation of a cellular structure of powders, which is observed in practice during spraying with water under pressure, confirms the correctness of the theoretical calculations. The results of the work can be used to substantiate the thermal regimes for obtaining powders with various structures, including amorphous ones.
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熔融水雾化法制备金属粉末时液滴的强制换热和冷却速率
介绍了采用粉末冶金法生产金属制品的工艺流程。在各种各样的粉末制造方法中,就效率和生产率而言,高压水喷射熔体是很好的区分,其中颗粒的几何形状和微观结构显著依赖于冷却速度,这与熔体滴-水-气相系统中传热的特性有关。然而,实验无法证实一种或另一种传热模式,这与颗粒尺寸小有关,在1 cm 3的喷雾区中颗粒的数量约为10 7。分析了溅射过程的热物理特性对金属液滴凝固速率的影响。在分析已知的传热传质规律和现象的基础上,估计了各种传热方式的传热系数、热流密度以及传热中传导、对流和辐射分量的贡献。结果表明,辐射传热的比例不大于0.1%。从理论上证明了液滴是在水沸腾的气泡模式下冷却的。对于工具钢,根据发达气泡模式下的传热系数计算出的颗粒冷却速率约为10.6 K/s。当产生的蒸汽膜被水流“撕裂”,模拟“假气泡”冷却时,在气泡或假气泡沸腾期间提供这样的冷却速率。在加压喷水过程中观察到粉末的胞状结构形成,证实了理论计算的正确性。这项工作的结果可以用来证实获得具有各种结构的粉末的热状态,包括非晶结构。
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审稿时长
8 weeks
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