Effect of addition of compatibilizer on mechanical, thermal and thermo-mechanical behavior of a polymer blend (PBT/ PBT(G)/ PTT) composite

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2022-01-27 DOI:10.1108/prt-11-2021-0132
Sundaram R.K., S. S., E. P
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Abstract

Purpose This study aims to reduce the interfacial tension by increasing the better adhesion between different immiscible polymers phases and also to evaluate the mechanical, thermal and thermo-mechanical behavior of the immiscible polymer blends. Design/methodology/approach The polymer blend composite (PBC) was prepared using a twin-screw extruder followed by injection molding. Two different kinds of PBC with compatibilizer (Ethylene-n-Butylacrylate-Glycidyl methacrylate) of varying compositions like polybutylene terephthalate + poly trimethylene terephthalate and polybutylene terephthalate (30% glass filled) + poly trimethylene terephthalate were prepared and material behavior at various test conditions were studied. The effect of glass fiber reinforcement on polymer blend and the interlocking effect by the compatibilizer between the polymer phases were also assessed. Findings Mechanical behavior of PBC was estimated by tensile, flexural and angular impact tests. Likewise, the thermal deflection was studied with the help of heat deflection temperature test. Thermo-mechanical behavior likes storage modulus, loss modulus and loss tangent were studied using the dynamic mechanical analysis test. Morphological analysis was characterized using field emission scanning electron microscopy. Originality/value This in turn makes the process easy to obtain the PBC having inherent mechanical, thermal and thermo-mechanically stable. And, it also enhances the mechanical properties like tensile, flexural and impact strength. Simultaneously, posse’s excellent heat deflection and thermo-mechanical behavior over a temperature range of 35–140ºC at a constant frequency of 5 Hz.
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增容剂的加入对聚合物共混物(PBT/PBT(G)/PTT)复合材料力学、热学和热机械性能的影响
目的本研究旨在通过提高不同不混溶性聚合物相之间更好的粘附性来降低界面张力,并评估不混溶聚合物共混物的力学、热学和热机械行为。设计/方法/方法使用双螺杆挤出机,然后注射成型制备聚合物共混复合材料(PBC)。制备了两种不同组成的相容剂(丙烯酸正丁酯-甲基丙烯酸缩水甘油酯)的PBC,如聚对苯二甲酸丁二醇酯+聚对苯二甲酸三甲酯和聚对苯二甲酸丁二酯(30%玻璃填充)+聚对苯二甲酸丙二醇酯,并研究了材料在不同试验条件下的性能。还评估了玻璃纤维增强对聚合物共混物的影响以及相容剂在聚合物相之间的互锁作用。通过拉伸、弯曲和角冲击试验对PBC的力学性能进行了评价。同样,借助热变形温度试验对热变形进行了研究。通过动态力学分析试验,研究了储能模量、损耗模量和损耗角正切等热机械性能。利用场发射扫描电子显微镜对形态分析进行了表征。独创性/价值这反过来又使工艺易于获得具有固有机械、热和热机械稳定性的PBC。此外,它还提高了拉伸、弯曲和冲击强度等力学性能。同时,posse在35-140ºC的温度范围内,在5的恒定频率下,具有出色的热偏转和热机械性能 赫兹。
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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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