Teak Leaf-Based Activated Carbon for Phosphate Removal

W. Astuti, Luluk Siti Zulaechah, L. Kristian
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引用次数: 2

Abstract

The use of detergent predictably causes large quantities of phosphate ion in water bodies. It is considered to trigger eutrophication, that creates a severe reduction in water quality. Adsorption using activated carbon is one of the effective methods for the removal of phosphate from wastewater. Recently, the use of microwave irradiation in activated carbon preparation is a promising alternative to replace conventional heating using a furnace. In this study, the use of microwave heating was compared to conventional heating. The result showed that pore of activated carbon was larger than that of the char and the activated carbon prepared using 30% of ZnCl2 had the adsorption performance higher than that of prepared using 20% of ZnCl2. The optimum adsorption occurred at pH 4 and the equilibrium was reached after 180 minutes. The Langmuir equilibrium model was more appropriate than the Freundlich equilibrium model. While the kinetics model analyzed using pseudo-first-order, pseudo-second-order, internal diffusion, and external diffusion indicated that the pseudo second order was most suitable for the adsorption of phosphate by teak leaf activated carbon.
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柚木叶基活性炭除磷研究
洗涤剂的使用可以预见会在水体中产生大量的磷酸盐离子。它被认为会引发富营养化,导致水质严重下降。活性炭吸附法是去除废水中磷酸盐的有效方法之一。近年来,利用微波辐照制备活性炭是一种很有前途的替代传统炉加热的方法。在本研究中,使用微波加热与传统加热进行了比较。结果表明,活性炭的孔隙大于炭的孔隙,30% ZnCl2的活性炭吸附性能高于20% ZnCl2的活性炭吸附性能。pH为4时吸附效果最佳,180min后达到吸附平衡。Langmuir均衡模型比Freundlich均衡模型更合适。而拟一阶、拟二阶、内扩散和外扩散的动力学模型分析表明,柚木叶活性炭对磷酸盐的吸附以拟二阶最合适。
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