The inhibition performance of anionic surfactant and zwitterionic surfactant toward the corrosion of carbon steel in NaCl solution

IF 1.5 4区 化学 Q4 CHEMISTRY, PHYSICAL International Journal of Chemical Kinetics Pub Date : 2023-05-16 DOI:10.1002/kin.21654
Chaodang Wu, Heng Yang, Shangqi Zhang, Peng Han, Haoran Sun, Zixiang Sheng, Haobo Yu, Xiaomei Ma
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Abstract

Carbon steel suffers from serious corrosion in NaCl solution, the development of effective inhibitor has become a hot issue. The corrosion inhibition performance of sodium lauryl ether sulfate (AES) and lauryl betaine (BS-12) and the mixture of the two inhibitors were studied using electrochemical and weight-loss methods. Results showed the corrosion inhibition efficiency order is AES + BS-12 > BS-12 > AES, the inhibition efficiency of the inhibitor increases with the increasing of concentration and the maximum inhibition efficiency is 95.9% in the solution with 200 mg L−1 AES + BS-12. Inhibitor can adsorb on Q235 surface through physical and chemical interactions and the adsorption obeys Langmuir isotherm. The migration of the corrosive ions to the metal is hindered and the metal is protected.

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阴离子表面活性剂和两性离子表面活性剂对碳钢在NaCl溶液中的缓蚀性能
碳钢在NaCl溶液中腐蚀严重,开发有效的缓蚀剂已成为研究的热点。采用电化学和失重法研究了十二烷基醚硫酸钠(AES)和十二烷基甜菜碱(BS-12)及其混合物的缓蚀性能。结果表明:缓蚀效率顺序为AES + BS-12 >BS-12祝辞在200 mg L−1 AES + BS-12的溶液中,抑制剂的抑制效率随浓度的增加而增加,最大抑制效率为95.9%。抑制剂通过物理和化学相互作用在Q235表面吸附,吸附过程遵循Langmuir等温线。阻止了腐蚀离子向金属的迁移,保护了金属。
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来源期刊
CiteScore
3.30
自引率
6.70%
发文量
74
审稿时长
3 months
期刊介绍: As the leading archival journal devoted exclusively to chemical kinetics, the International Journal of Chemical Kinetics publishes original research in gas phase, condensed phase, and polymer reaction kinetics, as well as biochemical and surface kinetics. The Journal seeks to be the primary archive for careful experimental measurements of reaction kinetics, in both simple and complex systems. The Journal also presents new developments in applied theoretical kinetics and publishes large kinetic models, and the algorithms and estimates used in these models. These include methods for handling the large reaction networks important in biochemistry, catalysis, and free radical chemistry. In addition, the Journal explores such topics as the quantitative relationships between molecular structure and chemical reactivity, organic/inorganic chemistry and reaction mechanisms, and the reactive chemistry at interfaces.
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Issue Information Force training neural network potential energy surface models Issue Information Folic acid as a green inhibitor for corrosion protection of Q235 carbon steel in 3.5 wt% NaCl solution Issue Information
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