EFFECT OF REACTION TIME ON VARIOUS PROPERTIES OF PALM OIL BIODIESEL IN CONTINUOUS BIODIESEL REACTOR

IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Journal of Oil Palm Research Pub Date : 2023-09-08 DOI:10.21894/jopr.2023.0040
V. Palaniselvam
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Abstract

Biodiesel consists of the fatty acid esters of simple alcohols, which pave the way to replace fossil diesel fuel with biodiesel in transportation. Using a continuous flow transesterification process is the viable option to produce biodiesel with reduced time and cost. In this study, different concentrations of catalyst potassium hydroxide at 1.0%, 1.5% and 2.0% were experimented to determine the higher recovery of biodiesel from palm oil. By increasing the methanol concentration 2-3 times higher than the stoichiometric requirement with respect to the catalyst concentration, the methyl ester yield increase gradually at a ratio of 0.5%. The maximum methyl ester yield was 96.0% for a 7.5:1.0 molar ratio. The samples taken at 10 min intervals were analysed for kinematic viscosity and specific gravity. In comparison with methyl ester yield, the maximum yield (96.0%) was obtained at 7.5:1.0 molar ratio and 2.0% catalyst concentration, which has minimum kinematic viscosity. For continuous transesterification of palm oil using static mixer, the optimum condition for maximum methyl ester yield (96.0%) was 7.5:1.0 molar ratio and 2.0% catalyst concentration.
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连续式生物柴油反应器中反应时间对棕榈油生物柴油各项性能的影响
生物柴油由简单醇的脂肪酸酯组成,这为生物柴油在交通运输中取代化石柴油铺平了道路。使用连续流动酯交换工艺是生产生物柴油的可行选择,减少了时间和成本。本研究通过对催化剂氢氧化钾浓度为1.0%、1.5%和2.0%的实验,确定了棕榈油中生物柴油的高回收率。将甲醇浓度相对于催化剂浓度提高到化学计量要求的2-3倍,甲酯收率以0.5%的比例逐渐增加。在7.5:1.0摩尔比下,甲酯收率最高达96.0%。每隔10分钟取一次样品,分析其运动粘度和比重。与甲酯收率相比,在7.5:1.0摩尔比、2.0%催化剂浓度、运动粘度最小的条件下,甲酯收率最高(96.0%)。采用静态混合器进行棕榈油连续酯交换反应时,最佳条件为7.5:1.0摩尔比和2.0%催化剂浓度,甲酯收率最高(96.0%)。
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来源期刊
Journal of Oil Palm Research
Journal of Oil Palm Research 农林科学-食品科技
CiteScore
2.60
自引率
30.80%
发文量
69
审稿时长
>12 weeks
期刊介绍: JOURNAL OF OIL PALM RESEARCH, an international refereed journal, carries full-length original research papers and scientific review papers on various aspects of oil palm and palm oil and other palms. It also publishes short communications, letters to editor and reviews of relevant books. JOURNAL OF OIL PALM RESEARCH is published four times per year, i.e. March, June, September and December.
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