{"title":"Adsorption of Rhodamine 6G Dye onto Al-MCM-41 and MCM-41 Mesoporous Materials","authors":"Houda Douba, O. Mohammedi, B. Cheknane","doi":"10.15255/kui.2022.001","DOIUrl":null,"url":null,"abstract":"The present study aimed to evaluate the potential of mesoporous silica MCM-41 and Al-MCM-41 (molar ratio Si/Al = 20) for the removal of Rhodamine 6G (Rh6G) from aqueous solution. The adsorbents were characterised by XRD, FTIR, SEM-EDX, BET, and UV-Raman. Obtained results related to XRD analysis indicated that the MCM-41 structure remained intact after the incorporation of Al species. Kinetic adsorption study showed that the higher removal (88.75 %, 26.62 mg g −1 ) of Rh6G dye was achieved by Al-MCM-41 at 60 min. FTIR analysis showed that hydrogen bonding played the dominant role in the Rh6G removal mechanism, while the pH results showed that electrostatic interaction was also a key factor. This study shows that the prepared mesoporous materials are inexpensive and efficient adsorbents for the removal of cationic dyes.","PeriodicalId":0,"journal":{"name":"","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15255/kui.2022.001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The present study aimed to evaluate the potential of mesoporous silica MCM-41 and Al-MCM-41 (molar ratio Si/Al = 20) for the removal of Rhodamine 6G (Rh6G) from aqueous solution. The adsorbents were characterised by XRD, FTIR, SEM-EDX, BET, and UV-Raman. Obtained results related to XRD analysis indicated that the MCM-41 structure remained intact after the incorporation of Al species. Kinetic adsorption study showed that the higher removal (88.75 %, 26.62 mg g −1 ) of Rh6G dye was achieved by Al-MCM-41 at 60 min. FTIR analysis showed that hydrogen bonding played the dominant role in the Rh6G removal mechanism, while the pH results showed that electrostatic interaction was also a key factor. This study shows that the prepared mesoporous materials are inexpensive and efficient adsorbents for the removal of cationic dyes.