Thermodynamic properties of methyl 4-(4-methoxyphenyl)-6-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate in organic solutions

IF 0.4 Q4 CHEMISTRY, ANALYTICAL French-Ukrainian Journal of Chemistry Pub Date : 2019-12-24 DOI:10.17721/fujcv7i2p1-8
O. Ridka, V. Matiychuk, I. Sobechko, N. Tyshchenko, M. Novyk, V. Sergeev, L. Goshko
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引用次数: 1

Abstract

The enthalpy and the entropy of dissolution of methyl 4-(4-methoxyphenyl)-6-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate in 2-propanol, ethyl acetate, acetonitrile, 2-propanone and benzene were determined from the temperature dependence of its solubility.The enthalpies and the entropies of mixing at 298 K were calculated taking into account the enthalpy of melting of the compound, determined via differential thermal analysis.The influence of the solvent on the solubility of the compound and on the corresponding enthalpy and entropy of mixing values was shown.
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4-(4-甲氧基苯基)-6-甲基-2-氧代-1,2,3,4-四氢嘧啶-5-羧酸甲酯在有机溶液中的热力学性质
从溶解度的温度依赖性测定了4-(4-甲氧基苯基)-6-甲基-2-氧代-1,2,3,4-四氢嘧啶-5-羧酸甲酯在2-丙醇、乙酸乙酯、乙腈、2-丙酮和苯中的溶解焓和熵。298K下的焓和混合熵是在考虑通过差热分析确定的化合物的熔融焓的情况下计算的。显示了溶剂对化合物溶解度以及相应的混合焓和熵值的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
French-Ukrainian Journal of Chemistry
French-Ukrainian Journal of Chemistry CHEMISTRY, ANALYTICAL-
自引率
0.00%
发文量
13
审稿时长
4 weeks
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