Why much of Chemistry may be indisputably non-bonded?

B. G. Oliveira
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Abstract

In this compendium, the wide scope of all intermolecular interactions ever known has been revisited, in particular giving emphasis the capability of much of the elements of the periodic table to form non-covalent contacts. Either hydrogen bonds, dihydrogen bonds, halogen bonds, pnictogen bonds, chalcogen bonds, triel bonds, tetrel bonds, regium bonds, spodium bonds or even the aerogen bond interactions may be cited. Obviously that experimental techniques have been used in some works, but it was through the theoretical methods that these interactions were validate, wherein the QTAIM integrations and SAPT energy partitions have been useful in this regard. Therefore, the great goal concerns to elucidate the interaction strength and if the intermolecular system shall be total, partial or non-covalently bonded, wherein this last one encompasses the most majority of the intermolecular interactions what leading to affirm that chemistry is debatably non-bonded.
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为什么很多化学物质都是无键的?
在本简编中,重新审视了迄今为止已知的所有分子间相互作用的广泛范围,特别强调了元素周期表中许多元素形成非共价接触的能力。可以列举氢键、二氢键、卤键、磷原键、硫属键、三烯键、四烯键、区域键、锂键或甚至气原键相互作用。显然,实验技术已经在一些工作中使用,但正是通过理论方法验证了这些相互作用,其中QTAIM积分和SAPT能量分配在这方面是有用的。因此,主要目标是阐明相互作用强度,以及分子间系统是完全、部分还是非共价键合的,其中最后一个包含了大多数分子间相互作用,从而确认化学是有争议的非键合。
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发文量
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审稿时长
12 weeks
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