Study on the adsorption of methylene blue by NaOH KH550 modified bagasse

X. Dai, Jiyuan Zhu
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Abstract

The chemical composition, thermal stability and crystallinity of NaOH/KH550 modified bagasse were studied using the infrared spectroscopic analysis, thermogravimetric analysis and X-ray diffractometry. After modification, the hemicellulose was removed and KH550 was grafted on the surface of the bagasse fibre effectively. Then, the modified bagasse was used as the adsorbent of methylene blue (MB) for the adsorption study. According to the results, the initial concentration of MB ranged from 10 to 200 mg/L at room temperature (25°C). And the removal rate of MB could reach 94% under the conditions of adsorbent dosage greater than or equal to 4 g/L, solution pH from 8 to 12 and an adsorption time longer than 60 minutes. Furthermore, the adsorption isotherm model and adsorption kinetic model of modified bagasse for MB were studied and the results showed that the adsorption isotherm accorded with Freundlich model and the adsorption kinetic model accorded with pseudo second-order kinetic equation.
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氢氧化钠KH550改性甘蔗渣对亚甲基蓝的吸附研究
采用红外光谱分析、热重分析和X射线衍射法对NaOH/KH550改性蔗渣的化学组成、热稳定性和结晶度进行了研究。改性后,半纤维素被去除,KH550被有效地接枝到蔗渣纤维表面。然后,以改性的蔗渣为吸附剂对亚甲基蓝进行吸附研究。根据结果,在室温(25°C)下,MB的初始浓度范围为10-200 mg/L。在吸附剂用量大于或等于4g/L、溶液pH为8-12、吸附时间大于60min的条件下,MB的去除率可达94%。此外,研究了改性蔗渣对MB的吸附等温线模型和吸附动力学模型,结果表明,其吸附等温线符合Freundlich模型,吸附动力学模型符合拟二阶动力学方程。
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