Synthesis and structure of 2,8-dimethyl-10,10-dichlorophenoxatellurine

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2021-01-01 DOI:10.1515/mgmc-2021-0002
Farzin Mostaghimi, Daniel Duvinage, E. Lork, J. Beckmann
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Abstract

Abstract The condensation of 4,4’-dimethyldiphenylether with tellurium tetrachloride yielded 2,8-dimethyl-10,10-dichlorophenoxatellurine (3), which was characterized by X-ray diffraction. Unlike the parent phenoxatellurine (1) and the 10,10,-dichlorophenoxatellurine (2) showing butterfly conformations, 3 reveals a planar ring structure.
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2,8-二甲基-10,10-二氯苯氧碲的合成与结构
摘要4,4’-二甲基二苯醚与四氯化碲缩合得到2,8-二甲基-10,10-二氯苯氧碲(3),并用X射线衍射对其进行了表征。与显示蝶形构象的母体苯并碲(1)和10,10,-二氯苯并碲(2)不同,3揭示了平面环结构。
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来源期刊
Main Group Metal Chemistry
Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC
CiteScore
4.10
自引率
27.80%
发文量
21
审稿时长
4 weeks
期刊介绍: This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.
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