Mechanism for the subglacial formation of cryogenic brines

Abstract

Abstract Cryogenic brines are under-studied, despite the fact that they may contain information about past ice-sheet behavior. Cryogenic brines form through cryoconcentration of seawater, although the specific setting and mechanism of formation have been debated. Previous conceptual models of brine formation require seawater isolation from the ocean in a closed basin experiencing freezing. We propose instead that they may form in pore spaces of marine sediments subjected to repeat cycles of ice-sheet advance and retreat. During periods of basal freezing, cryoconcentration produces hypersaline brines which experience downward flow driven by unstable density stratification. Our advection-diffusion model of porewater chemistry evolution successfully recreates the porewater chemistry of two deep Antarctic cores containing cryogenic brines (AND-1B and AND-2A), suggesting that cryogenic brines can be formed through the repeated isolation and cryoconcentration of marine waters within subglacial sediment pore spaces of modern and past ice sheets.