Phase evolution and burnability of cement raw meal

Abstract

The use of high-temperature X-ray diffraction (HT-XRD) to study the mass transfer of raw meal constituents towards forming clinker phases and the occurrence of free lime (calcium oxide), also known as burnability, was assessed. A measuring strategy with temperature ranging from 1000°C to 1450°C was developed and compared with a conventional burnability method. The free lime determined by the methods showed that HT-XRD produced good results for the evaluation of burnability. In addition, HT-XRD revealed the formation of intermediate phases, providing insight into early reactions in a cement kiln. The particle size of quartz was found to affect crystal expansion of the phase at a high temperature, subsequently affecting the formation of silica polymorphs. The different raw meals used in this study also indicate that the formation of different silica polymorphs affects the formation of C2S. The lack of knowledge regarding the influence of β-quartz on the reduction of free lime is highlighted.