Water absorption and mechanical properties of scots pine (Pinus sylvestris L.) wood samples treated with alkyl ketene dimer / boric acid combinations

Gaye Köse Demirel, A. Temiz
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Abstract

In order to build resistance against liquids, alkyl ketene dimer (AKD) is mostly employed in paper industry because it modified some properties of the paper such as wet strength and printability. AKD gets into a reaction with wood hydroxyl groups and the subsequent orientation of hydrocarbon chains effectively contributes to esterification. Thus, the dimensional stability of wood is improved with AKD addition. Additionally, boron compounds are quite useful in wood protection as environmentally friendly chemicals and they are effective as insecticides and fungicides. On the other hand, they have negative sides such as higher water solubility and leaching. These can be prevented by combining boron compounds with AKD. In this study, Scots pine (Pinus sylvestris L.) wood samples were impregnated with AKD (5%, 10%, 18%) and boric acid (3% BA) combinations. AWPA E4 standards were used for water absorption and dimensional stability test, and TS 2471 standards were used for compression strength parallel to the grain of the wood. The results indicated that AKD/BA combination had lower water absorption. In the mechanical test, the mechanical properties of the samples improved somewhat with the synergistic effect of AKD and BA.
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烷基烯二聚体/硼酸复合处理对苏格兰松木样吸水性能和力学性能的影响
为了增强对液体的抵抗力,烷基烯酮二聚体(AKD)主要用于造纸工业,因为它改变了纸张的一些性能,如湿强度和可印刷性。AKD与木材羟基发生反应,随后烃链的定向有效地促进了酯化反应。因此,添加AKD可以提高木材的尺寸稳定性。此外,硼化合物作为环境友好的化学品在木材保护方面非常有用,它们作为杀虫剂和杀菌剂也很有效。另一方面,它们具有较高的水溶性和浸出性等负面影响。这些可以通过将硼化合物与AKD结合来防止。在本研究中,用AKD(5%、10%、18%)和硼酸(3%BA)组合浸渍苏格兰松(Pinus sylvestris L.)木材样品。AWPA E4标准用于吸水性和尺寸稳定性测试,TS 2471标准用于平行于木材纹理的抗压强度。结果表明,AKD/BA组合具有较低的吸水率。在力学试验中,在AKD和BA的协同作用下,样品的力学性能有所改善。
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审稿时长
8 weeks
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