Raman analysis of chemisorbed tribofilm for metal-on-polyethylene hip joint prostheses

IF 1.6 Q4 ENGINEERING, BIOMEDICAL Biosurface and Biotribology Pub Date : 2021-05-25 DOI:10.1049/bsb2.12008
Risha Rufaqua, Martin Vrbka, Dušan Hemzal, Dipankar Choudhury, David Rebenda, Ivan Křupka, Martin Hartl
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引用次数: 1

Abstract

The biochemical reaction during the formation of lubricant film the in case of a cobalt-chromium ball on an ultrahigh-molecular weight polyethylene cup was studied. Three types of model synovial fluids and hyaluronic acid (HA) at physiologic concentrations were used in the experiment. The coefficient of friction was measured using a pendulum hip simulator, and Raman spectroscopy was used to perceive chemical reactions between the synovial fluid and implant material. Raman spectra evidenced that the three model fluids and HA chemisorbed onto the cobalt-chromium surface. An α-helix structure of the model fluid components was detected on the surface of the prosthesis.

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金属-聚乙烯髋关节假体化学吸附摩擦膜的拉曼光谱分析
捷克共和国教育、青年和体育部,资助/奖励号:FSI‐S‐20‐6443;GrantovñAgentura ÄŒeskéRepubliky,授予/奖号:20‐00483S摘要研究了超高分子量聚乙烯杯上钴铬球在润滑膜形成过程中的生化反应。实验采用三种模型滑液和生理浓度的透明质酸(HA)。采用摆髋关节模拟器测量摩擦系数,利用拉曼光谱感知滑液与植入材料之间的化学反应。拉曼光谱证明了三种模型流体和HA在钴铬表面发生化学吸附。在假体表面检测到模型流体成分的α‐螺旋结构。
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来源期刊
Biosurface and Biotribology
Biosurface and Biotribology Engineering-Mechanical Engineering
CiteScore
1.70
自引率
0.00%
发文量
27
审稿时长
11 weeks
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