Micro-scale Observation of Corrosion of Hot-Dip Aluminized 11% Cr Stainless Steel

IF 0.8 Q4 ELECTROCHEMISTRY Corrosion Science and Technology-Korea Pub Date : 2019-06-30 DOI:10.14773/CST.2019.18.3.73
Min-Seung Cho, Choong-Nyeon Park, Chan‐Jin Park
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Abstract

Hot-dip aluminized coating has been widely used to protect steel substrate against corrosion. In this study, the corrosion behavior of hot-dip aluminized type 409L (11% Cr) stainless steel (SS) was investigated using macro- and micro-scale polarization tests. An Al-Fe-Si alloy layer that was formed due to inter-diffusion of alloying elements between Al coating and SS substrate was observed between Al coating and 409L SS substrate. In both macro- and micro-scale polarization tests, the corrosion potential ( E corr ) of the 409L SS substrate was much nobler than that of the Al coating and alloy layer. E corr of the alloy layer was between that of Al coating and 409L SS substrate. This indicates that the alloy layer can act as a buffer between the more active Al coating and the nobler SS substrate for pit growth in aluminized SS. The presence of the alloy layer appears to be helpful in hindering pitting corrosion of aluminized SS.
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热浸镀铝11% Cr不锈钢腐蚀的微观观察
热浸镀铝涂层广泛应用于钢基体的防腐。采用宏观和微观极化试验研究了热浸镀铝409L (11% Cr)不锈钢(SS)的腐蚀行为。在Al涂层与409L SS衬底之间观察到合金元素在Al涂层与SS衬底之间相互扩散形成Al- fe - si合金层。在宏观和微观极化测试中,409L SS基板的腐蚀电位(E - corr)明显高于Al涂层和合金层。合金层的E角介于Al涂层和409L SS衬底之间。这表明合金层可以作为更活跃的Al涂层和更高尚的SS衬底之间的缓冲层,以促进镀铝SS的点蚀生长。合金层的存在似乎有助于阻止镀铝SS的点蚀。
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CiteScore
1.30
自引率
66.70%
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