Comparative Study on the Organic Solvent of IrO2–Ionomer Inks used for Spray Coating of Anode for Proton Exchange Membrane Water Electrolysis

IF 3 4区 工程技术 Q3 ELECTROCHEMISTRY Journal of electrochemical science and technology Pub Date : 2023-05-31 DOI:10.33961/jecst.2023.00185
H. Jung, Yongseok Jun, Kwanwoo Lee, Hyun S. Park, S. Cho, J. Jang
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Abstract

Currently, spray coating has attracted interest in the mass production of anode catalyst layers for proton exchange membrane water electrolysis (PEMWE). The solvent in the spray ink is a critical factor for the catalyst dispersion in ink, the microstructure of the catalyst layer, and the PEMWE performance. Herein, various pure organic solvents were examined as a substitute for conventional isopropanol-deionized water (IPA-DIW) mixture for ink solvent. Among the polar solvents that exhibited better IrO 2 dispersion over nonpolar solvents, 2-butanol (2-BuOH) was selected as a suitable candidate. The PEMWE single cells were fabricated using 2-BuOH at various ionomer contents, spray nozzle types
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质子交换膜电解阳极喷涂用iro2 -离子油墨有机溶剂的比较研究
目前,喷涂技术在大规模生产用于质子交换膜水电解(PEMWE)的阳极催化剂层方面引起了人们的兴趣。喷雾油墨中的溶剂是催化剂在油墨中的分散、催化剂层的微观结构和PEMWE性能的关键因素。本文研究了各种纯有机溶剂作为油墨溶剂的传统异丙醇-去离子水(IPA-DIW)混合物的替代品。在表现出比非极性溶剂更好的IrO2分散性的极性溶剂中,2-丁醇(2-BuOH)被选为合适的候选者。PEMWE单电池是使用2-BuOH在不同离聚物含量、喷嘴类型下制造的
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来源期刊
CiteScore
6.30
自引率
8.10%
发文量
44
期刊介绍: Covering fields: - Batteries and Energy Storage - Biological Electrochemistry - Corrosion Science and Technology - Electroanalytical Chemistry and Sensor Technology - Electrocatalysis - Electrochemical Capacitors & Supercapcitors - Electrochemical Engineering - Electrodeposition and Surface Treatment - Environmental Science and Technology - Fuel Cells - Material Electrochemistry - Molecular Electrochemistry and Organic Electrochemistry - Physical Electrochemistry - Solar Energy Conversion and Photoelectrochemistry
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