Jaewook Shin, J. Seo, Riley Yaylian, A. Huang, Y. Meng
{"title":"A review on mechanistic understanding of MnO2 in aqueous electrolyte for electrical energy storage systems","authors":"Jaewook Shin, J. Seo, Riley Yaylian, A. Huang, Y. Meng","doi":"10.1080/09506608.2019.1653520","DOIUrl":null,"url":null,"abstract":"ABSTRACT The demand for the large-scale storage system has gained much interest. Among all the criteria for the large-scale electrical energy storage systems (EESSs), low cost ($ k Wh−1) is the focus where MnO2-based electrochemistry can be a competitive candidate. It is notable that MnO2 is one of the few materials that can be employed in various fields of EESSs: alkaline battery, supercapacitor, aqueous rechargeable lithium-ion battery, and metal-air battery. Yet, the technology still has bottlenecks and is short of commercialisation. Discovering key parameters impacting the energy storage and developing systematic characterisation methods for the MnO2 systems can benefit a wide spectrum of energy requirements. In this review, history, mechanism, bottlenecks, and solutions for using MnO2 in the four EESSs are summarised and future directions involving more in-depth mechanism studies are suggested.","PeriodicalId":14427,"journal":{"name":"International Materials Reviews","volume":"65 1","pages":"356 - 387"},"PeriodicalIF":16.8000,"publicationDate":"2019-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/09506608.2019.1653520","citationCount":"107","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Materials Reviews","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/09506608.2019.1653520","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 107
Abstract
ABSTRACT The demand for the large-scale storage system has gained much interest. Among all the criteria for the large-scale electrical energy storage systems (EESSs), low cost ($ k Wh−1) is the focus where MnO2-based electrochemistry can be a competitive candidate. It is notable that MnO2 is one of the few materials that can be employed in various fields of EESSs: alkaline battery, supercapacitor, aqueous rechargeable lithium-ion battery, and metal-air battery. Yet, the technology still has bottlenecks and is short of commercialisation. Discovering key parameters impacting the energy storage and developing systematic characterisation methods for the MnO2 systems can benefit a wide spectrum of energy requirements. In this review, history, mechanism, bottlenecks, and solutions for using MnO2 in the four EESSs are summarised and future directions involving more in-depth mechanism studies are suggested.
期刊介绍:
International Materials Reviews (IMR) is a comprehensive publication that provides in-depth coverage of the current state and advancements in various materials technologies. With contributions from internationally respected experts, IMR offers a thorough analysis of the subject matter. It undergoes rigorous evaluation by committees in the United States and United Kingdom for ensuring the highest quality of content.
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