Morphological and Thermal Properties of Polystyrene/Poly (Vinyl Chloride) Blends

Nassira Tourta, A. Meghezzi, H. Boussehel
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引用次数: 1

Abstract

The present study investigated the morphological and thermal properties of polystyrene and polyvinyl chlorides blends (PS/PVC). The PS and PVC mixed by the solution casting by using cyclohexanone the ratios presented are 100/0,80/20,50/50,20/80 and 0/100 according to the weight of PS/PVC. Where the mixture formation is confirmed by Fourier transform infrared (FT-IR), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC) respectively. The spectral FT-IR results showed that the blend of PS/PVC did not have molecular reactions. The thermal gravimetry was used to achieve the thermal stability of the polymer blends. Two degrees of glass transition temperature were observed for each mixture. The results of DSC supported the absence of miscibility in the blend. The distribution of the phases in the virgin and blends was studied through scanning electron microscopy (SEM).
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聚苯乙烯/聚氯乙烯共混物的形态和热性能
研究了聚苯乙烯和聚氯乙烯共混物(PS/PVC)的形态和热性能。用环己酮将PS和PVC溶液浇铸后,根据PS/PVC的重量分别配制成100/0、80/20、50/50、20/80和0/100的比例。其中混合物的形成分别由傅里叶变换红外(FT-IR)、热重分析(TGA)和差示扫描量热法(DSC)证实。光谱FT-IR结果表明,PS/PVC共混物未发生分子反应。用热重法测定了聚合物共混物的热稳定性。每种混合物的玻璃化转变温度为2度。DSC结果支持混合物中不存在混相。通过扫描电子显微镜(SEM)研究了原始和共混物中相的分布。
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来源期刊
CiteScore
1.90
自引率
25.00%
发文量
32
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