M. Orzechowska, K. Rećko, D. Soloviov, U. Klekotka, M. Biernacka, D. Satuła, W. Olszewski, B. Kalska-Szostko, A. Beskrovnyy, K. Szymański
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引用次数: 1
Abstract
ABSTRACT The influence of the surface modification on the magnetism of 4–14 nm sized core and core/shell gallium ferrites obtained by different preparation methods (Massart’s and thermal decomposition from acetylacetonates) was studied. The physical properties of GaxFe3-xO4 were investigated in a wide range of Ga admixtures 0 ≤ x ≤ 1.5. Ga ions location at 8a or/and 16d positions of a spinel structure depends on the synthesis method and has a pronounced effect on the superparamagnetic properties of nanoparticles. Magnetization and Mössbauer experiments show the dominant superparamagnetic contribution for the nanoparticles with x > 0.8 with the blocking temperature TB significantly below 200 K. Surface-modified nanoferrites disclosed spontaneous magnetization that does not exceed 60 emu/g.
期刊介绍：
Phase Transitions is the only journal devoted exclusively to this important subject. It provides a focus for papers on most aspects of phase transitions in condensed matter. Although emphasis is placed primarily on experimental work, theoretical papers are welcome if they have some bearing on experimental results. The areas of interest include:
-structural phase transitions (ferroelectric, ferroelastic, multiferroic, order-disorder, Jahn-Teller, etc.) under a range of external parameters (temperature, pressure, strain, electric/magnetic fields, etc.)
-geophysical phase transitions
-metal-insulator phase transitions
-superconducting and superfluid transitions
-magnetic phase transitions
-critical phenomena and physical properties at phase transitions
-liquid crystals
-technological applications of phase transitions
-quantum phase transitions
Phase Transitions publishes both research papers and invited articles devoted to special topics. Major review papers are particularly welcome. A further emphasis of the journal is the publication of a selected number of small workshops, which are at the forefront of their field.
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