{"title":"Preparation and recognition property of an acyclic cucurbit[n]uril dimer","authors":"Fang Zhou, Da Ma, Yamin Liu","doi":"10.1007/s10847-022-01130-9","DOIUrl":null,"url":null,"abstract":"<div><p>A new acyclic cucurbit[<i>n</i>]uril (CB[<i>n</i>]) dimer is synthesized by copper-catalyzed azide-alkyne cycloaddition or “click” reaction. The acyclic CB[<i>n</i>] dimer possesses two cavities, and is able to encapsulate two guest molecules simultaneously. This dimer is discovered to be high affinity host molecule for a wide variety of dyes, pharmaceutical drugs and guest molecules.</p></div>","PeriodicalId":638,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":"102 5-6","pages":"487 - 491"},"PeriodicalIF":2.3000,"publicationDate":"2022-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-022-01130-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
引用次数: 1
Abstract
A new acyclic cucurbit[n]uril (CB[n]) dimer is synthesized by copper-catalyzed azide-alkyne cycloaddition or “click” reaction. The acyclic CB[n] dimer possesses two cavities, and is able to encapsulate two guest molecules simultaneously. This dimer is discovered to be high affinity host molecule for a wide variety of dyes, pharmaceutical drugs and guest molecules.
期刊介绍:
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.