Preparation and recognition property of an acyclic cucurbit[n]uril dimer

IF 2.3 4区 化学 Q2 Agricultural and Biological Sciences Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2022-01-21 DOI:10.1007/s10847-022-01130-9
Fang Zhou, Da Ma, Yamin Liu
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引用次数: 1

Abstract

A new acyclic cucurbit[n]uril (CB[n]) dimer is synthesized by copper-catalyzed azide-alkyne cycloaddition or “click” reaction. The acyclic CB[n] dimer possesses two cavities, and is able to encapsulate two guest molecules simultaneously. This dimer is discovered to be high affinity host molecule for a wide variety of dyes, pharmaceutical drugs and guest molecules.

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一种无环葫芦[n]脲二聚体的制备及其识别性能
采用铜催化叠氮化物-炔环加成或“咔嗒”反应合成了一种新的无环葫芦[n]脲(CB[n])二聚体。无环CB[n]二聚体具有两个空腔,能够同时包封两个客体分子。这种二聚体被发现是对多种染料、药物和客体分子具有高亲和力的宿主分子。
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来源期刊
CiteScore
3.30
自引率
8.70%
发文量
0
审稿时长
3-8 weeks
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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