Preparation of V2O5 Porous Hollow Spheres and Study on excellent cycling Stability of lithium Battery

Shimeng Zhang, Hongye Guan, Dapeng Li, Gengxin Zhang, Rui Yang, Liang Zhao, Haibin Sun, Zhicheng Lu, Jiacai Wen, Yujuan Dong
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引用次数: 1

Abstract

Through one-step simple polyol-assisted (ethylene glycol) process, V2O5 hollow micro-spheres about 3 micrometres in size were successfully synthesized. The structure is neat, the outer wall were porous. Testing its electrochemical properties with V2O5 hollowmaterials as cathode materia of lithium ion battery, the results showed that under the ratio of 1 C, the initial charge and discharge specifc capacity were 236.8 mAh g-1, 213 mAh g-1, even if after 100 cycles, the charge and discharge specifc capacity were still 220 mAh g-1 and 219.7 mAh g-1 respectively. Relative to the charge and discharge capacity of the second cycle, the keep rate were 93.2%, 92.9% respectively, has good cycle stability.
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V2O5多孔空心球的制备及锂电池优良循环稳定性研究
通过一步简单的多元醇辅助(乙二醇)工艺,成功地合成了尺寸约为3微米的V2O5空心微球。结构整洁,外墙多孔。用V2O5中空材料作为锂离子电池正极材料测试了其电化学性能,结果表明,在1C的比例下,初始充放电比容量分别为236.8mAh g-1和213mAh g-2,即使经过100次循环,充放电比仍分别为220mAh g-3和219.7mAh g-4。相对于第二次循环的充放电容量,保持率分别为93.2%和92.9%,具有良好的循环稳定性。
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