Crystal Structure of (2,2′-Bipyridine)(N-(1-naphthyl)methyl-1,3-propanediamine)platinum(II) Chloride

Abstract

The crystal structure of (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group C 2/ c and Z = 8 with cell parameters a = 23.3026(14)Å, b = 17.4118(12)Å, c = 12.3816(7)Å, β = 109.032(8) ° , V = 4749.1(6)Å 3 . The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0242 and 0.0490, respectively, for all 5435 independent reflections. In the crystal structure, disorder was observed for the N -(1-naphthyl)methyl-1,3-propanediamine moiety. Hydrogen-bond network was formed between the (2,2 ′ -bipyridine)( N -(1-naphthyl)methyl-1,3-propanediamine)platinum(II) cations and chloride anions.