{"title":"Chemical and morphological modification of softwood and hardwood surfaces by an oxygen glow discharge plasma","authors":"A. Jamali, P. Evans","doi":"10.1080/02773813.2022.2113539","DOIUrl":null,"url":null,"abstract":"Abstract High-energy radiation preferentially degrades cellulose and enriches lignin content at wood surfaces particularly in hardwoods. Accordingly, we hypothesize that a similar effect will occur at surfaces exposed to plasma. We test this hypothesis by plasma-treating pine and poplar veneers and assessing changes in the lignin and holocellulose-derived sugar-content of veneers; quantifying etching of pellets containing lignin and cellulose, and observing etching of different cell wall layers in pine and Homalium. The majority but not all of our results support our hypothesis. Lignin-rich regions of wood cell walls were easier to see after plasma treatment. We discuss the potential uses of plasma-etching for the study of wood ultrastructure and the creation of wood surfaces with self-bonding properties, and conclude that plasma-etching can be used as an alternative to chemical pretreatments for ultrastructural studies of the distribution of lignin in wood cell walls.","PeriodicalId":17493,"journal":{"name":"Journal of Wood Chemistry and Technology","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Wood Chemistry and Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/02773813.2022.2113539","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
引用次数: 0
Abstract
Abstract High-energy radiation preferentially degrades cellulose and enriches lignin content at wood surfaces particularly in hardwoods. Accordingly, we hypothesize that a similar effect will occur at surfaces exposed to plasma. We test this hypothesis by plasma-treating pine and poplar veneers and assessing changes in the lignin and holocellulose-derived sugar-content of veneers; quantifying etching of pellets containing lignin and cellulose, and observing etching of different cell wall layers in pine and Homalium. The majority but not all of our results support our hypothesis. Lignin-rich regions of wood cell walls were easier to see after plasma treatment. We discuss the potential uses of plasma-etching for the study of wood ultrastructure and the creation of wood surfaces with self-bonding properties, and conclude that plasma-etching can be used as an alternative to chemical pretreatments for ultrastructural studies of the distribution of lignin in wood cell walls.
期刊介绍:
The Journal of Wood Chemistry and Technology (JWCT) is focused on the rapid publication of research advances in the chemistry of bio-based materials and products, including all aspects of wood-based polymers, chemicals, materials, and technology. JWCT provides an international forum for researchers and manufacturers working in wood-based biopolymers and chemicals, synthesis and characterization, as well as the chemistry of biomass conversion and utilization.
JWCT primarily publishes original research papers and communications, and occasionally invited review articles and special issues. Special issues must summarize and analyze state-of-the-art developments within the field of biomass chemistry, or be in tribute to the career of a distinguished researcher. If you wish to suggest a special issue for the Journal, please email the Editor-in-Chief a detailed proposal that includes the topic, a list of potential contributors, and a time-line.