Construction of Dielectric Model of Nonaqueous Reactive Polyurethane Grouting Materials

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2022-12-20 DOI:10.1155/2022/1398724
Meili Meng, Zhanglan Chen
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Abstract

In order to reveal the dielectric properties of the nonaqueous reactive polyurethane grouting material, combined with the electron microscope test analysis, it can be seen that the nonaqueous reactive polyurethane material is a porous two-phase body composed of a polyurethane matrix and closed cells. At the microscopic scale, the porous two-phase physical model is established, and the dielectric model of the material is constructed on this basis. In order to verify the dielectric model, 40 groups of nonaqueous reactive polyurethane specimens with different densities were designed and prepared in this paper. The dielectric permittivity was measured by a vector network analyzer (VNA) with an open coaxial probe within the frequency range of 1050 MHz~5010 MHz for the first time, and the dielectric properties and influencing factors were revealed according to the test data. The result shows that the dielectric permittivity of nonaqueous reactive polyurethane materials increases with the increase of density, and decreases slightly with the increase of frequency. Compared with the three models of the Rule of Mixture, Clausius-Mossotti Model and Lichtenecker Model, the calculation accuracy of the Maxwell-Garnett Model is higher, and the calculation results are more consistent with the experimental results of nonaqueous reactive polyurethane grouting materials. The experimental results can be applied to the nondestructive testing of polyurethane grouting materials and provide reference and basis for the quality evaluation of polymer structures.
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非水反应聚氨酯注浆材料介电模型的建立
为了揭示非水反应性聚氨酯灌浆材料的介电性能,结合电子显微镜测试分析,可以看出非水反应型聚氨酯材料是由聚氨酯基体和闭孔组成的多孔两相体。在微观尺度上,建立了多孔两相物理模型,并在此基础上构建了材料的介电模型。为了验证介电模型,本文设计并制备了40组不同密度的非水反应性聚氨酯试件。介电常数是通过矢量网络分析仪(VNA)在1050的频率范围内用开放式同轴探针测量的 MHz~5010 并根据测试数据揭示了介电性能及其影响因素。结果表明,非水反应性聚氨酯材料的介电常数随密度的增加而增加,随频率的增加而略有下降。与混合律模型Clausius-Mossotti模型和Lichtenecker模型三种模型相比,Maxwell-Garnett模型的计算精度更高,计算结果与非水反应性聚氨酯灌浆材料的实验结果更为一致。实验结果可用于聚氨酯灌浆材料的无损检测,为聚合物结构的质量评价提供参考和依据。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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