Production of Urea/Acetylated-ligninsulfonate Matrix as SRFs and Investigation the Effect of Hydrodynamic Conditions on the Release Rate Using Biot Number

Abstract

This study aimed to investigate the effect of the hydrodynamic condition on the release rate of urea/acetylated lignin sulfonate (Ac-LS) matrix as slow-release fertilizers (SRFs). Therefore, two models were developed using the mass transfer balance for the finite/infinite volume of fluids, solving finite integral transform/separation of a variable. In these models, the Biot number that verified the hydrodynamic condition appeared. In the experimental section, the urea/Ac-LS matrix fertilizer was produced. The morphological, thermal, chemical, and mechanical properties of the LS, Ac-LS, urea, and urea/Ac-LS matrix were analyzed using Fe-SEM, TGA, XRD, and SANTAM. Finally, the nitrogen release of the matrix fertilizer was investigated at 25°C for different impeller speeds. The results showed that the thermal and mechanical resistance of urea/Ac-LS, with strong interaction, increased rather than pure urea or Ac-LS. The models were also validated using experimental data. The results further showed that in both states, the external resistance of the mass transfer decreased with increasing impeller speed, and the nitrogen release rate increased with increasing Biot number. It was also observed that, in a given hydrodynamic condition, initially, the release rate in the finite environment was less than the infinite; however, after a while, the type of environment did not affect the release rate