The research design of graphene inclusion on LDPE characterization

IF 2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Mechanical and Materials Engineering Pub Date : 2019-08-14 DOI:10.1186/s40712-019-0106-5
Maziyar Sabet, Hassan Soleimani
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引用次数: 7

Abstract

A progressive trend in instructional materials is the analytical plan and manufacture of fundamental operating equipment. LDPE/Gr nanocompounds were researched using various techniques such as Raman spectra (RS), XRD, SEM, and TEM based on Gr distribution, morphology, and crystal structure. The results presented by SEM showed that the addition of Grs was distributed homogeneously in the LDPE matrix and improved the crystallinity of the LDPE/Gr nanocompounds. Inclusion of Grs to LDPE launches crystallization by reducing the activation energy accompanied by increasing crystallization. Gr distribution in LDPE has considerably enhanced the nucleation of LDPE crystallization in nanocompound LDPE/Gr. The crystallization rates clearly increased to 0.5?wt% and continued to rise up to 3?wt% with Gr loading. Adding Gr to LDPE makes LDPE/Gr nanocompounds develop crystallinity Gr as a nucleating agent advances the process of crystallization, the size of crystallite, and the percentage of LDPE/Gr crystallinity throughout the nanocompounds with an additional Gr to the polymer matrix. This research also demonstrates that by further incorporation of Gr in the LDPE matrix, the activation energy of crystallinity is lowered. The inclusion of Gr extends crystallinity level and simultaneously creates local nanocompound lattice uniformity.

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石墨烯包合物对LDPE表征的研究设计
教学材料的一个进步趋势是基本操作设备的分析计划和制造。利用拉曼光谱(RS)、XRD、SEM和TEM等多种技术对LDPE/Gr纳米化合物的Gr分布、形貌和晶体结构进行了研究。SEM结果表明,Grs在LDPE基体中均匀分布,提高了LDPE/Gr纳米化合物的结晶度。在LDPE中掺入Grs,通过降低活化能同时增加结晶量来启动结晶。在纳米复合LDPE/Gr中,Gr在LDPE中的分布大大增强了LDPE结晶的成核性。结晶速率明显提高到0.5?Wt %,并继续上升至3?wt%与Gr加载。在LDPE中添加Gr使LDPE/Gr纳米化合物具有结晶性,作为成核剂的Gr通过在聚合物基体中添加额外的Gr,促进了结晶过程、晶体的大小和整个纳米化合物中LDPE/Gr结晶度的百分比。研究还表明,在LDPE基体中进一步掺入Gr,可以降低结晶活化能。Gr的加入扩大了结晶度,同时使纳米化合物的晶格局部均匀。
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来源期刊
CiteScore
8.60
自引率
0.00%
发文量
1
审稿时长
13 weeks
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