Crystal Structure of [Dihydrido-hexaphenylcarbodiphosphoran][chlorid][trichlorido-triphenylphosphino-platinat]

Abstract

refinement for all carbon atoms. The cell contains a heavily disordered THF molecule: therefore, the SQUEEZE function of PLATON 4 was applied. The SQUEEZE procedure omitted about 15.0 e/pm 3 ·10 –6 . These remaining electron densities could be assembled to two strongly disordered THF molecules: one of them with an occupation parameter of 1.0 and the other with an occupation parameter of The crystal structure of the salt [dihydrido-hexaphenylcarbodiphosphoran][chlorid][trichlorido-triphenylphosphino-platinat] was determined by X-ray crystallography. The title compound crystallizes in the monoclinic space group with the cell parameters a = 38.858(3)Å, b = 10.851(1)Å, c = 27.666(2)Å, α = 90 ° , β = 109.07(1) ° , γ = 90 ° , V = 11025(2)Å 3 , Z = 8. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F 2 to final values of R 1 = 0.0771 and wR 2 (all data)= 0.1732, T = 100(2)K.