{"title":"Structure evolution of vacancy-hydrogen complexes in a nickel-based single-crystal superalloy","authors":"Xiaozhi Tang, Xiao-Tong Li, Ya-Fang Guo","doi":"10.1080/09500839.2022.2145026","DOIUrl":null,"url":null,"abstract":"ABSTRACT The structural stability of vacancy-hydrogen complexes at the interface in nickel-based single-crystal superalloy is accessed mainly by calculating the activation energies associated with the evolution of their structures. It is found that the structure evolution and subsequent decomposition of the complex needs little time to be thermally activated at the service temperature of an aeroengine, and misfit dislocations at the interface significantly reduces the energy barrier for decomposition. Therefore, during the creep process, which is more severe at high temperatures, vacancies around misfit dislocations are not expected to enhance hydrogen interfacial segregation, although vacancy-hydrogen complexes are quite stable at room temperature.","PeriodicalId":19860,"journal":{"name":"Philosophical Magazine Letters","volume":"102 1","pages":"407 - 416"},"PeriodicalIF":1.2000,"publicationDate":"2022-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Philosophical Magazine Letters","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/09500839.2022.2145026","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
ABSTRACT The structural stability of vacancy-hydrogen complexes at the interface in nickel-based single-crystal superalloy is accessed mainly by calculating the activation energies associated with the evolution of their structures. It is found that the structure evolution and subsequent decomposition of the complex needs little time to be thermally activated at the service temperature of an aeroengine, and misfit dislocations at the interface significantly reduces the energy barrier for decomposition. Therefore, during the creep process, which is more severe at high temperatures, vacancies around misfit dislocations are not expected to enhance hydrogen interfacial segregation, although vacancy-hydrogen complexes are quite stable at room temperature.
期刊介绍：
Philosophical Magazine Letters is the rapid communications part of the highly respected Philosophical Magazine, which was first published in 1798. Its Editors consider for publication short and timely contributions in the field of condensed matter describing original results, theories and concepts relating to the structure and properties of crystalline materials, ceramics, polymers, glasses, amorphous films, composites and soft matter. Articles emphasizing experimental, theoretical and modelling studies on solids, especially those that interpret behaviour on a microscopic, atomic or electronic scale, are particularly appropriate.
Manuscripts are considered on the strict condition that they have been submitted only to Philosophical Magazine Letters , that they have not been published already, and that they are not under consideration for publication elsewhere.
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