Geochemical evolution of high-pH sodic salt pans in Central Otago, New Zealand

Abstract

ABSTRACT Soil-free sodic salt pans with local pH >10 have formed on loess and schist-derived clay surfaces in the semi-arid climate of Central Otago. This study identifies evaporative mineral distributions and associated variations in surface geochemistry, and these results are relevant to survival of rare halophytic plants on some of the pans. Evaporative salts on pan surfaces are dominated by NaCl from marine aerosols, and Na-sulphates and Na-carbonates. Some of the Na in evaporites was derived from alteration of schist-derived albite and Na-bearing smectite formed from albite. The high pH pan surfaces result from a combination of long-term (decades to millennia) albite alteration and short-term (minutes to months) Na-carbonate dissolution and recrystallisation. This muscovite is variably cemented by evaporative salts, and some crusts have abundant salt-dissolution voids. High pH has facilitated dissolution of aluminium and silica from albite and smectite, with evaporative precipitation of Al-oxyhydroxide contributing to crust cementation. Different dissolution rates of evaporative minerals during rain events and damp seasons results in differential mobility of salt components downslope. The salt pans are physically and chemically dynamic features that have formed on time scales of decades to centuries.