Preparation and Performance of CL-20-based Ultraviolet-curable High-explosive Ink and Its Application in Rigid Explosive Networks by Direct Ink Writing

IF 0.7 4区 工程技术 Q4 CHEMISTRY, APPLIED Central European Journal of Energetic Materials Pub Date : 2021-03-30 DOI:10.22211/CEJEM/134942
Ruigao Li, Wei-bing Li, Xiaode Guo, Li Liang, Yajun Wang, Wei-bing Li
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引用次数: 1

Abstract

To improve the groove charge consistency and density and to reduce the initiation synchronicity error of a rigid multi-point initiation explosive network, a CL-20-based ultraviolet (UV)-curable high-explosive ink, comprising 42 wt.% sub-micron CL-20, a 55.4 wt.% binder system (including 2.0 wt.% NC and 53.4 wt.% butyl acetate), and 2.6 wt.% UV-curable resin, based on direct ink writing (DIW) technology, was prepared. The properties of the composite sample deposited via DIW were characterized. The results indicated that the sample had good uniformity, with few defects, and a critical detonation size of around 1.5×0.283 mm. A six-point initiation explosive network was designed for the integration of DIW technology and precise press-loading of the charge. The network featured six pre-pressed booster pellets with the same charge density (ρ0 = 1.89 g·cm−3, 95.8% of theoretical maximum density) as the output end charges, and a groove channel charged by DIW and press-loading. This procedure increased the density of the booster charge in the groove channels to 1.890 g·cm−3, effectively improved the consistency of the charge density between the groove Central European Journal of Energetic Materials ISSN 1733-7178; e-ISSN 2353-1843 Copyright © 2021 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland 87 Preparation and Performance of CL-20-based Ultraviolet-curable High-explosive... Copyright © 2021 Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, Poland channels and the output ends and lowered the initiation synchronicity error of the network to 62 ns. The network can initiate a jetting projectile charge (JPC) with good shape and small lateral offset, implying that the network initiation capability and synchronization meet the operational requirements of JPC
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CL-20基紫外线固化高爆油墨的制备、性能及其在直接油墨书写刚性炸药网络中的应用
为了提高槽装药的一致性和密度,减小刚性多点起爆炸药网络的起爆同步性误差,采用直接书写(DIW)技术,制备了一种由42 wt.%亚微米CL-20、55.4 wt.%粘结剂体系(包括2.0 wt.% NC和53.4 wt.%乙酸丁酯)和2.6 wt.% UV固化树脂组成的CL-20基紫外固化高爆油墨。对DIW沉积的复合材料的性能进行了表征。结果表明,样品均匀性好,缺陷少,临界爆轰尺寸在1.5×0.283 mm左右。为了将DIW技术与装药精确压装相结合,设计了六点起爆药网。该网络的输出端装药为6粒相同装药密度(ρ0 = 1.89 g·cm−3,为理论最大装药密度的95.8%)的预压助推器颗粒,采用DIW和压装方式进行装药。该方法将槽道内升压装药的密度提高到1.890 g·cm−3,有效地提高了槽内装药密度的一致性;e-ISSN 2353-1843版权所有©2021 Łukasiewicz研究网络-波兰工业有机化学研究所87 cl -20基紫外固化高爆剂的制备与性能版权所有©2021 Łukasiewicz研究网络-波兰工业有机化学研究所通道和输出端,并将网络的起始同步性误差降低到62 ns。该网络能以良好的外形和较小的侧向偏移量起爆射弹装药,表明该网络的起爆能力和同步性满足射弹装药的作战要求
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来源期刊
Central European Journal of Energetic Materials
Central European Journal of Energetic Materials CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
1.80
自引率
25.00%
发文量
0
审稿时长
>12 weeks
期刊介绍: CEJEM – the newest in Europe scientific journal on energetic materials It provides a forum for scientists interested in the exchange of practical and theoretical knowledge concerning energetic materials: propellants, explosives and pyrotechnics. The journal focuses in particular on the latest results of research on various problems of energetic materials. Topics: ignition, combustion and detonation phenomenon; formulation, synthesis and processing; analysis and thermal decomposition; toxicological, environmental and safety aspects of energetic materials production, application, utilization and demilitarization; molecular orbital calculations; detonation properties and ballistics; biotechnology and hazards testing CEJEM presents original research and interesting reviews. Contributions are from experts in chemistry, physics and engineering from leading research centers in Europe, America and Asia. All submissions are independently refereed by Editorial Board members and by external referees chosen on international basis.
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