New Glasses in the PbCl2–PbO–B2O3 System: Structure and Optical Properties

IF 2.7 Q1 MATERIALS SCIENCE, CERAMICS Ceramics-Switzerland Pub Date : 2023-06-27 DOI:10.3390/ceramics6030083
D. Butenkov, A.V. Bakaeva, K. Runina, I. Krol, Maria Uslamina, A. Pynenkov, O. Petrova, I. Avetissov
{"title":"New Glasses in the PbCl2–PbO–B2O3 System: Structure and Optical Properties","authors":"D. Butenkov, A.V. Bakaeva, K. Runina, I. Krol, Maria Uslamina, A. Pynenkov, O. Petrova, I. Avetissov","doi":"10.3390/ceramics6030083","DOIUrl":null,"url":null,"abstract":"New oxychloride lead borate glasses in the xPbCl2–(50-0.5x)PbO–(50-0.5x)B2O3 system were synthesized with a maximum lead chloride content of 40 mol%. The characteristic temperatures and mechanical and optical properties were studied. The incorporation of lead chloride led to a significant expansion of the transparency range in the UV (up to 355 nm) and IR regions (up to 4710 nm). Decreases in the Vickers hardness, density, and glass transition temperature were the consequences of a change in the structure. The studied glasses are promising materials for photonics and IR optics. The structure of the PbCl2–PbO–B2O3 system was analyzed in detail using vibrational spectroscopy and X-ray diffraction.","PeriodicalId":33263,"journal":{"name":"Ceramics-Switzerland","volume":" ","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2023-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics-Switzerland","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ceramics6030083","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

Abstract

New oxychloride lead borate glasses in the xPbCl2–(50-0.5x)PbO–(50-0.5x)B2O3 system were synthesized with a maximum lead chloride content of 40 mol%. The characteristic temperatures and mechanical and optical properties were studied. The incorporation of lead chloride led to a significant expansion of the transparency range in the UV (up to 355 nm) and IR regions (up to 4710 nm). Decreases in the Vickers hardness, density, and glass transition temperature were the consequences of a change in the structure. The studied glasses are promising materials for photonics and IR optics. The structure of the PbCl2–PbO–B2O3 system was analyzed in detail using vibrational spectroscopy and X-ray diffraction.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
PbCl2–PbO–B2O3体系中的新型玻璃:结构和光学性质
在xPbCl2–(50-0.5x)PbO–(50-0.5 x)B2O3体系中合成了新的氯氧化铅硼酸铅玻璃,最大氯化铅含量为40 mol%。对其特征温度、力学性能和光学性能进行了研究。氯化铅的掺入导致UV(高达355nm)和IR区域(高达4710nm)中的透明度范围的显著扩展。维氏硬度、密度和玻璃化转变温度的降低是结构变化的结果。所研究的玻璃是用于光子学和红外光学的有前景的材料。使用振动光谱和X射线衍射对PbCl2–PbO–B2O3体系的结构进行了详细分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
3.00
自引率
7.10%
发文量
66
审稿时长
10 weeks
期刊最新文献
Non-Invasive On-Site XRF and Raman Classification and Dating of Ancient Ceramics: Application to 18th and 19th Century Meissen Porcelain (Saxony) and Comparison with Chinese Porcelain Biomechanical Behavior of Lithium-Disilicate-Modified Endocrown Restorations: A Three-Dimensional Finite Element Analysis Preparation and Characterization of Freeze-Dried β-Tricalcium Phosphate/Barium Titanate/Collagen Composite Scaffolds for Bone Tissue Engineering in Orthopedic Applications Ceramic Filters for the Efficient Removal of Azo Dyes and Pathogens in Water Bioinspired Mechanical Materials—Development of High-Toughness Ceramics through Complexation of Calcium Phosphate and Organic Polymers
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1