Organic porous solid as promising iodine capture materials

IF 2.3 4区 化学 Q2 Agricultural and Biological Sciences Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2022-01-23 DOI:10.1007/s10847-022-01128-3
Ya-Nan Yu, Zheng Yin, Li-Hui Cao, Yang-Min Ma
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引用次数: 9

Abstract

Facing the dual pressure of increasing global energy demand and heavy task in carbon emission reduction on schedule, nuclear renaissance is being seriously discussed as transitive choice before full renewable energy supply, yet there is a crucial concern about radioactive safety. The treatment of radioactive iodine is particularly important and challenging because of its high ratio in fission product, extremely long radioactive periods up to several millions of years, as well as easy diffusion in the whole ecosystem. Given that several challenge including easy sublimation, high water solubility, diverse existing species of I2, I, I2n+1 and organic iodine, biocompatibility and strong aggregation in thyroid, rapid capture and permanent storage of iodine is requested. Comparing to inorganic adsorbents of zeolite and inorganic–organic hybrid MOFs, pure organic porous solid are emerging as new and promising iodine capture material. Their high iodine affinity and adsorption capacity, good stability in various environments, facile modification and functionalization, intrinsic structural flexibility guaranteed the outstanding performance in iodine capture. Four main categories of organic cages, supramolecular framework connected by weak interaction, covalent organic frameworks and polymers with intrinsic microporosity were summarized and discussed, from the viewpoints of design principles, iodine capture performance, and adsorbent-iodine interactions. As the main prospect, we hope this work will attracting more researchers to study porous organic materials and address the challenge of effective capture of radioactive iodine.

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有机多孔固体是很有前途的碘捕获材料
面对全球能源需求不断增长和碳减排任务如期完成的双重压力,核能复兴作为可再生能源全面供应前的过渡选择正在被认真讨论,但其放射性安全问题却备受关注。放射性碘的处理尤其重要和具有挑战性,因为它在裂变产物中所占比例高,放射性周期极长,长达数百万年,并且易于在整个生态系统中扩散。考虑到易升华、高水溶性、I2、I−、I2n+1−和有机碘种类多样、生物相容性和在甲状腺中的强聚集性等挑战,需要快速捕获和永久储存碘。与无机吸附剂沸石和无机-有机杂化MOFs相比,纯有机多孔固体是一种新型的有前途的碘捕获材料。它们具有高的碘亲和力和吸附能力,在各种环境中具有良好的稳定性,易于修饰和功能化,固有的结构灵活性保证了它们在碘捕获方面的优异性能。从设计原理、吸附性能、吸附剂-碘相互作用等方面对有机笼、弱相互作用连接的超分子框架、共价有机框架和具有固有微孔的聚合物四大类进行了综述和讨论。作为主要前景,我们希望这项工作能够吸引更多的研究人员来研究多孔有机材料,并解决有效捕获放射性碘的挑战。
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来源期刊
CiteScore
3.30
自引率
8.70%
发文量
0
审稿时长
3-8 weeks
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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