A Novel Process for Manufacturing Vanadium Dioxide(VO2) as a resource of Vanadium Electrolyte from Vanadium Pentoxide(V2O5)

IF 1.5 Q3 GEOSCIENCES, MULTIDISCIPLINARY Geosystem Engineering Pub Date : 2022-07-04 DOI:10.1080/12269328.2022.2156398
B. Kim, Taegong Ryu, Jihyuk Choi, Tae Jun Park, Hankwon Chang, JeongHyun Yoo, Chang-Youl Suh, S. Cho, K. Roh
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引用次数: 0

Abstract

ABSTRACT A vanadium electrolyte for energy storage is generally prepared by dissolving vanadium pentoxide (V2O5) in sulfuric acid using oxalic acid ((COOH)2) as a reducing agent. However, there is a disadvantage that the dissolution rate in the sulfuric acid solution of V2O5 is very slow. In this study, a new process for producing vanadium dioxide (VO2), which has the faster dissolution rate than V2O5 in sulfuric acid solution, was developed. Vanadium dioxide (VO2) could be used in the production of a vanadium electrolyte for energy storage. The process developed in the study has the advantages of being economical and simple as compared to the existing process for producing VO2 from V2O5 using hydrogen or carbon monoxide as a reducing agent.
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五氧化二钒(V2O5)生产二氧化钒(VO2)的新工艺
用于储能的钒电解质通常是通过将五氧化二钒(V2O5)溶解在硫酸中,使用草酸((COOH)2)作为还原剂来制备的。然而,存在V2O5在硫酸溶液中的溶解速率非常慢的缺点。在本研究中,开发了一种生产二氧化钒(VO2)的新工艺,该工艺在硫酸溶液中的溶解速度比V2O5更快。二氧化钒(VO2)可用于生产用于能量存储的钒电解质。与使用氢气或一氧化碳作为还原剂从V2O5生产VO2的现有工艺相比,本研究中开发的工艺具有经济和简单的优点。
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来源期刊
Geosystem Engineering
Geosystem Engineering GEOSCIENCES, MULTIDISCIPLINARY-
CiteScore
2.70
自引率
0.00%
发文量
11
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