Lang Xu, Jiapei Shen, Qing Sun, Jian Zhang, Jiawei Sheng
{"title":"Effect of glass frits on ceramifiable properties of polyethylene composites","authors":"Lang Xu, Jiapei Shen, Qing Sun, Jian Zhang, Jiawei Sheng","doi":"10.1002/fam.3131","DOIUrl":null,"url":null,"abstract":"<p>Ceramification of polymer composites is an excellent method for enhancing the flame retardancy of the materials. The low temperature softening glass frit added in the composites plays a key role in the ceramification process of the composites. Ceramizable polyethylene (PE)/wollastonite fiber (WF) composites are processed by mixing with three types of glass frit. The ceramic residues formed were characterized by the linear shrinkage, weight loss, flexural strength, apparent porosity, and self-supporting property measurements. The density and strength of the ceramic increased with the increasing sintering temperature, but were affected by the wettability and fluidity of the glass frit. The addition of glass frit can increase the thermal decomposition temperature of PE. X-ray diffraction (XRD) analysis found the form of a new phase of hydroxyapatite (Ca<sub>10</sub>(PO<sub>4</sub>)<sub>6</sub>(OH)<sub>2</sub>) in the ceramifiable PE/WF composites by adding phosphate glass frit, which improved the self-supporting properties of the ceramic residues.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"47 7","pages":"874-883"},"PeriodicalIF":2.0000,"publicationDate":"2023-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fire and Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/fam.3131","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
Abstract
Ceramification of polymer composites is an excellent method for enhancing the flame retardancy of the materials. The low temperature softening glass frit added in the composites plays a key role in the ceramification process of the composites. Ceramizable polyethylene (PE)/wollastonite fiber (WF) composites are processed by mixing with three types of glass frit. The ceramic residues formed were characterized by the linear shrinkage, weight loss, flexural strength, apparent porosity, and self-supporting property measurements. The density and strength of the ceramic increased with the increasing sintering temperature, but were affected by the wettability and fluidity of the glass frit. The addition of glass frit can increase the thermal decomposition temperature of PE. X-ray diffraction (XRD) analysis found the form of a new phase of hydroxyapatite (Ca10(PO4)6(OH)2) in the ceramifiable PE/WF composites by adding phosphate glass frit, which improved the self-supporting properties of the ceramic residues.
期刊介绍：
Fire and Materials is an international journal for scientific and technological communications directed at the fire properties of materials and the products into which they are made. This covers all aspects of the polymer field and the end uses where polymers find application; the important developments in the fields of natural products - wood and cellulosics; non-polymeric materials - metals and ceramics; as well as the chemistry and industrial applications of fire retardant chemicals.
Contributions will be particularly welcomed on heat release; properties of combustion products - smoke opacity, toxicity and corrosivity; modelling and testing.
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