Trace ambient levels of particulate mercury and its sources at a rural site near Delhi

Abstract

Atmospheric particle-bound mercury levels were measured in PM₁₀ aerosols (HgP) at a rural site (Mahasar, Haryana) during winter 2014–15 and summer 2015. The PM₁₀ HgP was determined by?using Differential Pulse Anodic Stripping Voltammetry through standard addition methods while the trace metals were determined by using an Atomic Absorption Spectroscopy. The mass concentrations of HgP varied from 591 to 1533?pg/m³ with an average of 1009?±?306?pg/m³ during the winter, while the mass concentrations of HgP varied from 43 to 826?pg/m³ with an average of 320?±?228?pg/m³ during the summer. However, it is difficult to assess whether these levels are harmful or not because there is no standard value available as National Ambient Air Quality Standard. The higher concentrations of HgP during winters were possibly due to favourable local meteorological conditions for the stagnation of particulate matter in the lower atmosphere and the increased emissions from existing natural or anthropogenic sources, regional sources and long-range transportation. Relatively low concentrations of HgP during summer might be due to increased mixing heights as well as scavenging effect because some light to heavy rain events were observed during summer time sampling. However, among other metals determined, the concentration of HgP was the lowest during both the seasons. The study may be useful in assessing the health impacts of PM₁₀ HgP and other metals.