Determination of Kinetic Parameters in the Biosorption of Chromium (VI) in Aqueous Solution

C. Tejada-Tovar, Á. Villabona-Ortíz, R. Ortega-Toro
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引用次数: 6

Abstract

he contamination of aquatic bodies by heavy metals is a growing environmental problem, making more critical the study and development of new technologies and materials that can be used for the removal of this type of pollutants. Thus, adsorption arises using residual materials as a sustainable alternative for the solution to this problem. In the present study, the use of plantain peels in the adsorption of Cr (VI) in a batch system is proposed, establishing the kinetics of the process at different temperature conditions, particle size and amount of adsorbent. The fit of the data was done using the theoretical models of pseudo-first-order, pseudo-second-order and Elovich. From the data, it is established that the pseudo-second-order and Elovich models show a better adjustment, so that the adsorption in the material occurs on two adsorption sites and that such process is related to chemical adsorption. The maximum adsorption capacity of Cr (VI) was found at a condition of 0.0306 g, 0.6775 mm and 55°C at a time of 420 min establishing the efficient use of plantain peels for the removal of the ion metallic in the studio.
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水溶液中铬(VI)生物吸附动力学参数的测定
重金属对水体的污染是一个日益严重的环境问题,因此研究和开发可用于去除这类污染物的新技术和材料变得更加重要。因此,使用残余材料作为解决这一问题的可持续替代方案产生了吸附作用。在本研究中,提出了在分批系统中使用芭蕉皮吸附Cr(VI),建立了在不同温度条件、颗粒大小和吸附剂用量下的过程动力学。利用伪一阶、伪二阶和Elovich的理论模型对数据进行了拟合。从数据中可以确定,伪二阶和Elovich模型显示出更好的调整,使得材料中的吸附发生在两个吸附位点上,并且这种过程与化学吸附有关。在0.0306 g、0.6775 mm和55°C的条件下,在420分钟的时间内发现了Cr(VI)的最大吸附能力,这证明了在工作室中有效利用芭蕉皮去除金属离子。
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