Crystallization of Sodium Borosilicate Glass with the Addition of Cr2O3

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass Physics and Chemistry Pub Date : 2023-05-24 DOI:10.1134/S1087659622601083
M. Yu. Konon, I. G. Polyakova, A. S. Saratovskii, D. P. Danilovich, I. N. Anfimova
{"title":"Crystallization of Sodium Borosilicate Glass with the Addition of Cr2O3","authors":"M. Yu. Konon,&nbsp;I. G. Polyakova,&nbsp;A. S. Saratovskii,&nbsp;D. P. Danilovich,&nbsp;I. N. Anfimova","doi":"10.1134/S1087659622601083","DOIUrl":null,"url":null,"abstract":"<p>Glass composition of 6Na<sub>2</sub>O 22B<sub>2</sub>O<sub>3</sub>·70SiO<sub>2</sub>·2Cr<sub>2</sub>O<sub>3</sub> is studied by scanning electron microscopy, X‑ray powder diffractometry (XRPD), and differential thermal analysis, depending on the duration of heat treatment at a temperature of 550°C. It is established that during heat treatment for 24–96 h, a phase separation structure with interpenetrating phases is formed in the studied glass, and a crystalline phase of eskolaite—Cr<sub>2</sub>O<sub>3</sub> is also formed. With the maximum heat treatment duration of 96 h, cristobalite is formed in the bulk of the glass, which is accompanied by a decrease in the glass transition temperature of the low-viscosity phase. In this case, the intensity of eskolaite peaks decreases. Cr<sub>2</sub>O<sub>3</sub> and SiO<sub>2</sub> crystallize apparently due to the substance of the low-viscosity phase.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1087659622601083","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 2

Abstract

Glass composition of 6Na2O 22B2O3·70SiO2·2Cr2O3 is studied by scanning electron microscopy, X‑ray powder diffractometry (XRPD), and differential thermal analysis, depending on the duration of heat treatment at a temperature of 550°C. It is established that during heat treatment for 24–96 h, a phase separation structure with interpenetrating phases is formed in the studied glass, and a crystalline phase of eskolaite—Cr2O3 is also formed. With the maximum heat treatment duration of 96 h, cristobalite is formed in the bulk of the glass, which is accompanied by a decrease in the glass transition temperature of the low-viscosity phase. In this case, the intensity of eskolaite peaks decreases. Cr2O3 and SiO2 crystallize apparently due to the substance of the low-viscosity phase.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Cr2O3对硼硅酸钠玻璃结晶的影响
通过扫描电子显微镜、X射线粉末衍射(XRPD)和差热分析,研究了6Na2O 22B2O3·70SiO2·2Cr2O3的玻璃成分,这取决于在550℃下热处理的持续时间。结果表明,在热处理24 ~ 96 h的过程中,研究玻璃形成了相分离的互穿相结构,并形成了硅石- cr2o3的结晶相。在最大热处理时间为96 h时,玻璃整体形成方石云石,并伴随着低粘度相玻璃化转变温度的降低。在这种情况下,escolaite峰的强度降低。Cr2O3和SiO2由于存在低粘度相而明显结晶。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
期刊最新文献
Cluster Self-Organization of Intermetallic Systems: Cluster-Precursors K13, K11, K4, and K3 for the Self-Assembly of Crystal Structures Ce56Ni24Si44-mS124 and Ba10La2Si12-oP48 Effect of the Elemental Composition of Optical Glasses on the Quantitative Characteristics of X-Ray and Gamma Radiation Attenuation Synthesis and Research of Electrolyte and Electrode Materials in CeO2–Nd2O3 and Gd2O3–La2O3–SrO–Ni(Co)2O3 – δ Systems for Medium-Temperature Fuel Cells Production of Block Catalysts for Carbon Monoxide Oxidation Using Additive Technologies Concentration Effect of Glass Former on the Lumenescene Properties of Tb3+-Ions Doped Na2O–CaO–B2O3–TeO2 Glasses for Laser Applications
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1