VOLATILE ORGANIC COMPOUNDS AND METALS ADSORPTION CAPACITY OF WOOD BARK-BASED ACTIVATED CARBONS

Abstract

This study was conducted to investigate the applicability of wood bark-based activated carbon (AC) for the adsorption of metal ions and volatile organic compounds (VOC) from the atmosphere. Contents of Fe and Al in the AC made with coconut shell, and the bark of larch and cork oak (CSA, LBA and COA, respectively) were higher than those of the unexposed AC and increased with the exposure to various indoor/outdoor spaces when compared to the unexposed AC. However, Fe and Al contents of the exposed AC, which is a coal-based one used as a control (SAA), were lower and scarcely higher than the unexposed SAA. From the results, it is evident that the wood bark-based AC examined in this study is more effective to adsorb metals than SAA. The SEM-EDS analysis exhibited prominent metal-adsorptivity of COA, although its total surface area and pore volume were lower than those of SAA. Total VOC-adsorptivity was the highest in COA followed by CSA, CBA (cypress bark activated carbon), LBA and SAA. In conclusion, wood bark-based AC can be utilized as an effective adsorbent for the removal of metals and VOC from the atmosphere. The optimum AC is COA, an industrial by-product, in view of the techno-economic aspect.