Facile preparation of robust superhydrophobic coating on concrete surface through “all-covalent” strategy

Abstract

Purpose The purpose of this study is to prepare a robust superhydrophobic coating on concrete substrate with remarkable chemical and mechanical durability through “all-covalent” strategy. Design/methodology/approach Amino-modified silica nano/micro-particles were prepared through two synthetic steps. “All-covalent” strategy was introduced to prepare a robust superhydrophobic coating on concrete surface via a “all-in-one” dispersion and a simple spraying method. The successful construction of the products was confirmed by Fourier transform infrared spectroscopy, water contact angles (WCA), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM). The concrete protective properties were verified by solution immersion test, pull-off test and rapid chloride migration coefficient test. The mechanical durability was tested by falling sand impact. Findings Hierarchical structures combined with the low-surface-energy segments lead to typically superhydrophobic coating with a WCA of 156° and a sliding angle of 1.3°. The superhydrophobic coating prepared through “all-covalent” strategy not only improves chemical and mechanical durability but also achieves higher corrosion and wear resistance than the comparison sample prepared by physically blending strategy. More importantly, the robust superhydrophobic coating showed excellent adhesion and protective performance of concrete engineerings. Practical implications This new “all-covalent” superhydrophobic coating could be applied as a concrete protective layer with properties of self-cleaning, anti-graffiti, etc. Originality/value Introduction of both silica nanoparticles and silica microparticles to prepare a robust superhydrophobic coating on concrete surface through “all-covalent” strategy has not been systematically studied previously.