Gibbs energy minimisation model for the austenite-ferrite phase transformation in Fe-C-X-Y alloys

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Philosophical Magazine Letters Pub Date : 2021-06-03 DOI:10.1080/09500839.2021.1909166
Alexandre Mathevon, M. Perez, V. Massardier, D. Fabrègue, P. Chantrenne, P. Rocabois
{"title":"Gibbs energy minimisation model for the austenite-ferrite phase transformation in Fe-C-X-Y alloys","authors":"Alexandre Mathevon, M. Perez, V. Massardier, D. Fabrègue, P. Chantrenne, P. Rocabois","doi":"10.1080/09500839.2021.1909166","DOIUrl":null,"url":null,"abstract":"ABSTRACT A new model has been developed to predict austenite ferrite transformation kinetics in steels. For each alloying element, the concentration profile is computed solving a unique diffusion equation (including the 2 phases and the interface). The interface is described assuming linear variation of chemical potentials, saving thus computational time. Interface motion is driven by the minimisation of Gibbs energy. The model naturally reproduces the transition between thermodynamic equilibria (Para equilibrium, Local equilibrium with negligible partitioning, Local equilibrium) during heating. The validity of the model for reverse transformation has been validated on ternary and quaternary systems Fe-C-(Mn-Si-Mo) on decarburisation experiments.","PeriodicalId":19860,"journal":{"name":"Philosophical Magazine Letters","volume":"101 1","pages":"232 - 241"},"PeriodicalIF":1.2000,"publicationDate":"2021-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/09500839.2021.1909166","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Philosophical Magazine Letters","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/09500839.2021.1909166","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 3

Abstract

ABSTRACT A new model has been developed to predict austenite ferrite transformation kinetics in steels. For each alloying element, the concentration profile is computed solving a unique diffusion equation (including the 2 phases and the interface). The interface is described assuming linear variation of chemical potentials, saving thus computational time. Interface motion is driven by the minimisation of Gibbs energy. The model naturally reproduces the transition between thermodynamic equilibria (Para equilibrium, Local equilibrium with negligible partitioning, Local equilibrium) during heating. The validity of the model for reverse transformation has been validated on ternary and quaternary systems Fe-C-(Mn-Si-Mo) on decarburisation experiments.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Fe-C-X-Y合金奥氏体-铁素体相变的吉布斯能量最小化模型
摘要建立了一个预测钢中奥氏体-铁素体转变动力学的新模型。对于每个合金元素,通过求解唯一的扩散方程(包括两相和界面)来计算浓度分布。假设化学势的线性变化来描述界面,从而节省了计算时间。界面运动是由吉布斯能的最小化驱动的。该模型自然地再现了加热过程中热力学平衡(准平衡、可忽略分配的局部平衡、局部平衡)之间的转变。在Fe-C-(Mn-Si-Mo)三元系和四元系脱碳实验中验证了反变换模型的有效性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Philosophical Magazine Letters
Philosophical Magazine Letters 物理-物理:凝聚态物理
CiteScore
2.60
自引率
0.00%
发文量
25
审稿时长
2.7 months
期刊介绍: Philosophical Magazine Letters is the rapid communications part of the highly respected Philosophical Magazine, which was first published in 1798. Its Editors consider for publication short and timely contributions in the field of condensed matter describing original results, theories and concepts relating to the structure and properties of crystalline materials, ceramics, polymers, glasses, amorphous films, composites and soft matter. Articles emphasizing experimental, theoretical and modelling studies on solids, especially those that interpret behaviour on a microscopic, atomic or electronic scale, are particularly appropriate. Manuscripts are considered on the strict condition that they have been submitted only to Philosophical Magazine Letters , that they have not been published already, and that they are not under consideration for publication elsewhere.
期刊最新文献
Martensitic transformation of reversed austenite in a low-carbon 7Ni steel Machine-learning-assisted analysis of highly transient X-ray imaging sequences of weld pools Assessment of Bayesian guidance strategy to develop bake-hardening ferritic steel Perspective on descriptors of mechanical behaviour of cubic transition-metal carbides and nitrides Design of carbide free bainitic steels for hot rolling practices
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1