Double-Wavelength-Switchable Molecular Self-Assembly of a Photoacid and Spirooxazine in an Aqueous Solution

IF 4.8 2区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry Letters Pub Date : 2023-10-20 DOI:10.1021/acs.jpclett.3c02392
Alexander Zika, Mohit Agarwal, Ralf Schweins and Franziska Gröhn*, 
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Abstract

Quadruple-switchable nanoscale assemblies are built by combining two types of water-soluble molecular photoswitches through dipole–dipole interaction. Uniting the wavelength-specific proton dissociation of a photoacid and ring-opening of an anionic spirooxazine results in an assembly that can be addressed by irradiation with two different wavelengths: pH and darkness.

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水溶液中光酸和螺恶嗪的双波长可切换分子自组装。
四重可切换纳米级组件是通过偶极-偶极相互作用将两种类型的水溶性分子光开关结合在一起构建的。将光酸的波长特异性质子解离和阴离子螺恶嗪的开环结合起来,可以通过用两种不同波长(pH和黑暗)照射来解决组装问题。
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来源期刊
The Journal of Physical Chemistry Letters
The Journal of Physical Chemistry Letters CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
9.60
自引率
7.00%
发文量
1519
审稿时长
1.6 months
期刊介绍: The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.
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