Microstructure and corrosion behavior of welded joint between 2507 super duplex stainless steel and E690 low alloy steel

Liwei Wang , Yi Ding , Qiankun Lu , Zhao Guo , Yuxi Liu , Zhongyu Cui
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Abstract

Microstructure and corrosion behavior of welded joints between super duplex stainless steel 2507 and low alloy steel E690 were characterized herein. The joints are composed of base metal and heat affected zone (HAZ) of the two steels, weld metal, and dilution zone at the interface between weld metal and HAZ of E690 steel. Concentration gradients of Fe, Ni, Cr, and Mo exist between fusion boundary and Type-II boundary, and martensite band with a high hardness is formed. The changes of microstructure, element diffusion in different regions, and local acidification in E690 HAZ lead to heterogeneous corrosion attacks on the welded joints in artificial seawater. After long-term exposure, a corrosion groove is generated at the HAZ of E690 adjacent to the interface, where high stress corrosion cracking vulnerability is expected.

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2507超级双相不锈钢与E690低合金钢焊接接头的组织与腐蚀行为
对超双相不锈钢2507与低合金钢E690焊接接头的组织和腐蚀行为进行了表征。接头由母材和两种钢的热影响区、焊缝金属以及E690钢焊缝金属和热影响区界面处的稀释区组成。Fe、Ni、Cr和Mo的浓度梯度存在于熔合边界和II型边界之间,并形成具有高硬度的马氏体带。E690热影响区的微观组织变化、元素在不同区域的扩散和局部酸化导致焊接接头在人工海水中受到非均匀腐蚀。长期暴露后,E690界面附近的HAZ处会产生腐蚀槽,预计此处会出现高应力腐蚀开裂脆弱性。
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