Investigation of alkali-silica reaction on mortars with alternative binder systems: Alkali activated Slags and Celitement

Abstract

This study investigates the resistance against alkali-silica reaction (ASR) of two alternative binder systems, alkali-activated slag (AAS) and Celitement (Celite). Experimental studies on expansion and mechanical strength are carried out. Coupled kinetic and equilibrium thermodynamic modeling is used to clarify the role of binder chemistry on ASR. It was observed that under accelerated conditions OPC based mortars were more susceptible to ASR compared to AAS and Celite-based mortars. Based on experimental and modeling results, a correlation is shown between the dissolution of silica and the degree of expansion, but no correlation was found between the predicted amount of ASR products and the measured degree of expansion. Finally, the expansion degree could only be correlated with the reduction in compressive and flexural tensile strength for ASR-exposed samples.