Influence of Acid–Base Characteristics of Hierarchical Cu/Zr-MTW Zeolites on their Catalytic Properties in 1,3-Butadiene Production from Ethanol–Water Mixtures
O. V. Larina, M. M. Kurmach, P. I. Kyriienko, L. M. Alekseenko, O. V. Shvets, S. O. Soloviev
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引用次数: 0
Abstract
The nature of mineralizing agent (HF, NH4F) and the Si/F ratio in the synthesis conditions is found to affect the formation of Zr- and Cu-containing acid sites on the surface of zirconium-containing hierarchical zeolites (Cu/Zr-MTW) modified by copper (2 wt.%). It is shown that in the conversion of 50 and 80 vol.% ethanol the highest yield of 1,3-butadiene is achieved in the presence of Cu/Zr-MTW (NH4F, Si/F = 4) catalyst, which is characterized by higher total surface acidity according to TPD-NH3.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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