T. N. Nekrasova, N. A. Nesterova, A. I. Fischer, I. I. Gavrilova, A. P. Katasonova, E. F. Panarin
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引用次数: 0
Abstract
Water-soluble copolymers of sodium styrene sulfonate and 4-methacrylamidosalicylic acid of 93.7 mol % composition have been synthesized, and their interaction with terbium and gadolinium ions has been investigated to fabricate luminescent probes promising for their visualization in biomedical research. It has been shown that, in aqueous solutions in the copolymer concentration range 0.15–1.7 mg mL–1 and at the ratio [Tb3+]/[COO–] = 1, water-soluble luminescent metal polymer complexes with a luminescence lifetime of 823 µs are formed. When Tb3+ ions are partially replaced in the complex by Gd3+ ions, bimetallic complexes with intense luminescence are formed.
期刊介绍:
Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.